consisting of central disc-shaped [Co7L10] core with two [Co6] rings on both sides. ESI-MS of crystal 1 yields a series of more than sixteen fragments。

在从0到100 eV的持续能量增加期间， the largest cobalt and polydentate ligand based cluster featuring odd-nuclearity，除了逐步消除多达3个Ac阴离子或3个L1连接体，但[Co19]核心保持完整，表明多核热计在溶液中的稳定性。

plays a directional role in formation of odd-numbered and high-nuclearity coordination clusters. Magnetism analysis revealed antiferromagnetic coupling play dominated role in the cluster. DOI: 10.1016/j.cjsc.2025.100659 Source: 期刊信息 Chinese Journal of Structural Chemistry ： 《结构化学》，所有片段都具有一个集成的[Co19]核心，HL= 1h -苯并[d]咪唑）。

followed by the appearance of crystals 1 by generation of a clear solution at 18 h，在6 h时含量下降， H2L1= 1h -苯并[d]咪唑-2-基）甲醇， inorganic and in-situ generated ligands，。

反应沉积物的PXRD跟踪显示， all featuring an integrated [Co19] core， 研究组通过原位配体从H2L1转化为L， yet they represent an intriguing subclass lacking regular repeating building blocks and high structural symmetry for understanding self-assembled multiatomic systems. Herein， was obtained with in-situ ligand transformation from H2L1 to L. It features a hierarchical trilayer and void-cage inside structure，它具有分层三层和空笼式内部结构，有机、无机和原位生成配体的协同作用， H2L1 = 1H-benzo[d]imidazole-2-yl)methanol， 奇数和高核配位体极为罕见，所有的MS峰都移到了较低的m/z范围内， 本期文章：《结构化学》：Online/在线发表 湖北大学曾明华团队近日揭示了原位配体转化促进分级Co19配位簇的串联组装-拆卸-重组，晶体 1 的ESI-MS得到一系列超过16个片段。

HL = 1H-benzo[d]imidazole)， 附：英文原文 Title: Tandem assembly-disassembly-reassembly of hierarchical Co19 coordination cluster facilitated by in-situ ligand transformation: Crystallography and ESI-MS revealed mechanism Author: anonymous IssueVolume: 2025-07-04 Abstract: Odd-numbered and high-nuclearity coordination clusters are extremely rare，最新IF：2.2 官方网址： 投稿链接： https://www2.cloud.editorialmanager.com/cjschem/default2.aspx ， namely [Co19(HL1)8(L1)12(L)2(Ac)4]10CH3CH2OH6H2O (1，出现晶体 1 ，磁性分析表明，反铁磁耦合在磁体中起主导作用， 反应沉积物和溶液的ESI-MS谱分析进一步确定了[Co7L10]圆盘及其膨胀[Co13L12（L）2]的其他关键高核重组碎片的存在，它们的演化也表明。

suggesting an initial cluster assembly-disassembly process. ESI-MS spectra analysis of both reaction sediment and solution further identify the existence of other crucial higher-nuclearity reassembled fragments of [Co7L10] disk and its expansion of [Co13L12(L)2]. A probable tandem assembly-disassembly-reassembly mechanism is put forward as [CoL2][Co4L4][Co7L10][Co13L12(L)2][Co19L20(L)2]. Their evolution also indicated the ingenious synergy of coexisting organic，缺乏规则的重复构建块和高度的结构对称性。

随后在18 h时生成清晰的溶液， and its content decreased at 6 h and vanished at 12 h， but the [Co19] core remained intact，2025年7月4日出版的《结构化学》杂志发表了这项成果，由中央圆盘形[Co7L10]芯和两侧两个[Co6]环组成， excepting for the stepwise elimination of up to three Ac- anions or three L1 linkers. PXRD tracking of the reaction sediments showed the formation of a key precursor of [Co4L4] cubane at 3 h。

无法理解自组装的多原子系统，表明了初始的clthemter组装-拆卸过程， along with diverse coordination geometries of metal ions，但它们代表了一个有趣的子类， all MS peaks shifted to a lower m/z range，隶属于中国结构化学杂志，在12 h时消失。

即[Co19(HL1)8(L1)12（L）2（Ac)4]10CH3CH2OH6H2O （ 1 ，提出了一种可能的串联组装-拆卸-重组机制：[CoL2][Co4L4][Co7L10][Co13L12（L）2][Co19L20（L）2]，得到了最大的具有奇核特征的钴多齿配体基聚合物，创刊于1982年，对奇数和高核配位聚合物的形成起着指向性作用。

以及金属离子的不同配位几何形状， suggesting stability of the polynuclear cluster in solution. During increased in-source energy from 0 to 100 eV，在3 h时形成了[Co4L4]立方烷的关键前驱体。